((Dimethylamino)methyl)ferrocene — Research Review
CAS: 1271-86-9. View product page
Research Overview
This review analyzes 8 peer-reviewed publications on ((Dimethylamino)methyl)ferrocene, spanning synthetic methodology, structural characterization, and applied research.
Key Findings
- Cyclic voltammetry and electrochemical cycling experiments in acetonitrile/LiPF confirmed that this molecule undergoes oxidation at relatively high potential and exhibits moder
- Ferrocene, since its discovery in 1951, has been extensively exploited as a redox probe in a variety of processes ranging from solution chemistry, medicinal chemistry, supramolecul
- A Hirshfeld surface analysis indicated that the most significant contributions to the crystal packing of 2 are from H...H , C...H/H...C and Se...H/H...Se contacts, while those
Synthetic Studies
1. A Physical Organic Chemistry Approach to Developing Cyclopropenium-Based Energy Storage Materials for Redox Flow Batteries.
Acc Chem Res ()
ConspectusRedox flow batteries (RFBs) represent a promising modality for electrical energy storage. In these systems, energy is stored via paired redox reactions of molecules on opposite sides of an electrochemical cell. Thus, a central objective
2. Ferrocene as an iconic redox marker: from solution chemistry to molecular electronic devices
arXiv preprint ()
Ferrocene, since its discovery in 1951, has been extensively exploited as a redox probe in a variety of processes ranging from solution chemistry, medicinal chemistry, supramolecular chemistry, surface chemistry to solid-state molecular electronic an
3. Synthesis, structural, characterization and Hirshfeld analysis of a bisselenide and a zinc complex of a new hemilabile ferrocenylbisphosphane, [FeC(5)
Acta Crystallogr C Struct Chem ()
The novel hemilabile ferrocenylbisphosphane 1,1'-bis(bis2-[(dimethylamino)methyl]phenylphosphanyl)ferrocene, [FeC(5)H(4)P(C(6)H(4)CH(2)NMe(2)-o)(2)(2)] (1), was synthesized by reacting bis(dichlorophosphanyl)ferrocene, [FeC(5)H(4)(PCl(2))(2)] with
4. Comparing the reactivity of isomeric phosphinoferrocene nitrile and isocyanide in Pd(ii) complexes: synthesis of simple coordination compounds vs. pre
Dalton Trans ()
Isomeric phosphinoferrocene ligands, viz. 1'-(diphenylphosphino)-1-cyanoferrocene (1) and 1'-(diphenylphosphino)-1-isocyanoferrocene (2), show markedly different coordination behaviours. For instance, the reactions of 1 with [PdCl2(MeCN)2] and [(L
5. A new P,S-coordinating ferrocenyl ligand: synthesis of a precursor and its coordination compounds with Pd(II) and Pt(II).
Acta crystallographica. Section C, Structural chemistry ()
In our ongoing development of ferrocene ligands, 1-dimethylamino-2-(diphenylphosphinothioyl)ferrocene is being used as a convenient building block to obtain racemic or enantiomerically pure ligands. Using this building block in large excess allowed t
6. Synthesis and Structural Characterisation of an N-Phosphanyl Ferrocene Carboxamide and its Ruthenium, Rhodium and Palladium Complexes.
Chempluschem ()
[((Diphenylphosphanyl)amino)carbonyl]ferrocene (1) has been synthesized and coordinated to light platinum metals, ruthenium, rhodium and palladium, in diverse coordination modes. Specifically, compound 1 was used to prepare the following phosphane
Additional Research
1. Quantum interference in coherent tunnelling through branched molecular junctions containing ferrocene centers
arXiv preprint ()
In our theoretical study where we combine a nonequilibrium Green's function (NEGF) approach with density functional theory (DFT) we investigate branched compounds containing ferrocene moieties in both branches which due to their metal centers are des
2. Impact of ionization of ferrocene: EOES of alpha- and beta- electrons and the fingerprint orbital of ferrocenium
arXiv preprint ()
Ionization process of ferrocene (Fc) to produce ferrocenium cation (Fc+) has been debated as much as the eclipsed and staggered ferrocene conformers. The present quantum mechanical study reveals that removal of an electron does not apparently affect
Sources: PubMed, CrossRef. 8 papers. 2026-05-25